In this study, the QA/QC test for the combined application of DNPH cartridge – HPLC/UV method was investigated in the collection and analysis of formaldehyde in air using three types of DNPH cartridge samplers made by three independent manufacturers. For these experiments, gaseous standards of formaldehyde (FA) were prepared at 7 concentration levels that fell in the range of 44.1~3400 nmol/mol. According to our analysis, the levels of cartridge blank (0.13 ~ 0.26 ng) are found to be fairly high to require routine check up for each experiment. The recovery patterns of FA were highly comparable between different cartridge products, when standard gases are supplied in the concentration range up to 177 nmol/mol. All 3 types of DNPH cartridge exhibited highly similar recovery rates at concentrations below 1.7 ㎛ol/mol, while the maximum recovery was attained from the product B. The overall results of our study suggest that one should calibrate the samples in the optimal range of recovery with routine check up of blank values. Keywords：DNPH cartridge, Formaldehyde, Recovery rate, Breakthrough