The purpose of this study was to investigate the odor arising from the Cheong-ju industrial complex area for odor materials confirmation, and to predict the impact of the odor in the residential area using the CALPUFF Model. Among the odor causing substances in the area with a rising number of collective complaints due to odor, methyl sulfide, acetaldehyde, propionaldehyde, n-buthylaldehyde, n-valeraldehyde and styrene were detected. Odor causing substances detected in the area surrounding the industrial complex include ammonia, hydrogen sulfide, n-buthylaldehyde, toluene, xylene, benzene and styrene. Using the CALPUFF Model, it was predicted that 1hr average was 3.981~7.553 OU/m3 and 24hr average was 1.753~2.359 OU/m3. In terms of odor intensity, the predicted 1hr average was 0.6~0.9 and the 24hr average was 0.2~0.4. Keywords : Odor pollution, CALPUFF Model, Complex odor, Designated offensive odor substances, Industrial complex area