The purpose of this study is to optimize an emission test method for building materials and to understand the characteristics of total volatile organic compounds (TVOC) and carbonyl compounds emission from building materials, especially solid-phase building materials, using a small chamber test method. As a result of the evaluation for small chamber system, temperature and humidity was maintained constantly at 24.5℃, 50.2%. The background concentration of total volatile organic compounds and formaldehyde were also controlled below 20㎍/㎥ and 0.5㎍/㎥, respectively. Air leakage of emission test chamber and the duplicate precision between two emission test chambers were satisfied. As a result of evaluation for sampling and analysis system (such as the breakthrough test), repeatability of response factor, and retention time in GC/MS and HPLC, desorption efficiency, method detection limits were excellent. The concentration of total volatile organic compounds emitted from wallpapers (made of PVC) was higher at 25℃ than at 23℃. Also, the concentration of formaldehyde emitted from floorings made from non-PVC (wood-based) was higher at 25℃ than at 23℃. On the other hand, there was not a significant difference between the concentrations of total volatile organic compounds emission from wallpaper (made of PVC) which was stored for 2 weeks at 25℃ and 4℃ with tight sealing. In conclusion, emission characteristics of TVOC and formaldehyde from solid-phase building materials would be expected to apply to the plan for the management of indoor air quality. keywords：Optimize emission test method, Small chamber, Solid-phase building materials, TVOC